No, the purpose of the key functions is to enable you to find your car in the dark (approach lighting) or to illuminate your way to your front door after parking the car (home safe). The lamps that will illuminate are fixed in the logic of the function as detailed in the car handbook. Headlamps are illuminated under the home safe function, so that you can see where you are going as you walk away from the car. They are not illuminated under the approach function, as they could disrupt your night vision as you walk towards the car. If you walked into an object or tripped as a result of not being able to see where you were going, Volvo would find the ensuing litigation unwelcome
Depending on your location, it may be illegal for DRLs to be illuminated unless the engine is running, and that will also be determined by the CEM programming according to the intended market for the car.